Affinage mechanistic annotation for CGAS (human) Affinage Affinage (Claude Sonnet reading pass + Opus synthesis pass) 27 citations

Affinage mechanistic annotation for CGAS (human)

Current model (mechanistic narrative)

cGAS is a cytosolic and nuclear nucleic-acid sensor that initiates innate immune and cell-fate responses by detecting aberrant DNA and synthesizing the second messenger 2'3'-cGAMP, which activates downstream STING signaling PMID:23722159. A DNA-induced structural switch converts cGAS into an active nucleotidyl transferase that forms cGAMP, and beyond B-form dsDNA it also recognizes cytosolic RNA:DNA hybrids [PMID:23722159, PMID:25425575]. Activation requires assembly of a 2:2 cGAS-dsDNA complex, and cGAS is held inactive when bound to the nucleosome acidic patch via two conserved arginines that occlude its dsDNA-binding surface and lock it as a monomer [PMID:32911482, PMID:32913000]. This sets up cGAS as a sensor of genome instability: it accumulates at micronuclei following nuclear envelope rupture and is activated by exposed chromatin in a cell-cycle-dependent manner to drive interferon-stimulated gene expression, cellular senescence, and the senescence-associated secretory phenotype [PMID:28738408, PMID:28533362]. During mitosis, when cGAS contacts chromatin, it is restrained by nucleosome competition, Aurora kinase B-mediated N-terminal hyperphosphorylation, and blockade of oligomerization, while in arrested cells cGAS-dependent IRF3 phosphorylation can instead promote apoptosis [PMID:31299200, PMID:33542149]. cGAS activity is set by an extensive layer of regulators and modifications: G3BP1 promotes large activating cGAS complexes and DNA binding, MRE11-RAD50-NBN displaces cGAS from nucleosome sequestration to enable activation by oncogenic stress and ionizing radiation, and ZBP1 nucleates a cGAS-RIPK1-RIPK3 complex to sense mitochondrial genome instability [PMID:30510222, PMID:38200309, PMID:37352855]. Inhibitory modifications include DNA-PK phosphorylation, ZDHHC18-mediated C474 palmitoylation, PRMT1-mediated Arg133 methylation, PARP1-mediated PARylation at Asp191, and AARS2-mediated lactylation, while HERC5-mediated ISGylation enhances oligomerization and activity [PMID:33273464, PMID:35438208, PMID:37193698, PMID:35460603, PMID:39322678, PMID:38421872]. Nuclear cGAS is degraded by the CRL5-SPSB3 ubiquitin ligase via a C-terminal NN degron, and in the nucleus cGAS suppresses homologous recombination by interacting with PARP1 through poly(ADP-ribose) to impede the PARP1-Timeless complex [PMID:38418882, PMID:30356214]. cGAS also acts as a selective autophagy receptor for micronuclei through an LC3B-interacting region, and its DNA sensing is tuned by RNA-promoted phase separation [PMID:33752561, PMID:36382803]. The activated pathway has broad physiological consequences, including STING-dependent autophagy, antitumor immunity through cGAMP transfer to myeloid cells, and age-associated microglial dysfunction and neurodegeneration [PMID:30842662, PMID:31665636, PMID:37532932].

Affinage mechanism profile (Affinage's own GO/Reactome grounding)

Dated findings (citation-anchored)

Year Confidence Finding PMIDs Journal
2013 High Crystal structure of cGAS alone and in complex with DNA, ATP, and GTP revealed that cGAS catalyzes dinucleotide (cGAMP) formation via a DNA-induced structural switch; cGAS possesses structural similarity to OAS1 and contains a unique zinc thumb that recognizes B-form dsDNA. PMID:23722159 Nature
2014 High cGAS recognizes cytosolic RNA:DNA hybrids in addition to dsDNA; recombinant cGAS produced cGAMP upon RNA:DNA hybrid recognition in vitro, and THP-1 knockout cells confirmed this response is mediated entirely through the cGAS-STING pathway. PMID:25425575 The EMBO journal
2017 High cGAS localizes to micronuclei arising from genome instability; breakdown of the micronuclear envelope leads to rapid cGAS accumulation at chromatin, and cGAS is activated by chromatin in a cell-cycle-dependent manner, triggering interferon-stimulated gene expression in micronucleated cells. PMID:28738408 Nature
2017 High cGAS is essential for cellular senescence and the senescence-associated secretory phenotype (SASP); deletion of cGAS accelerated immortalization of MEFs and abrogated SASP induced by DNA-damaging agents. cGAS localizes in the cytoplasm of non-dividing cells but enters the nucleus and associates with chromatin DNA during mitosis. PMID:28533362 Proceedings of the National Academy of Sciences of the United States of America
2018 High Nuclear cGAS suppresses homologous recombination (HR) DNA repair. DNA damage induces nuclear translocation of cGAS dependent on importin-α; phosphorylation of cGAS at Tyr215 by B-lymphoid tyrosine kinase (BLK) facilitates cytosolic retention. In the nucleus, cGAS is recruited to DSBs, interacts with PARP1 via poly(ADP-ribose), and the cGAS-PARP1 interaction impedes formation of the PARP1-Timeless complex, suppressing HR. PMID:30356214 Nature
2018 High G3BP1 physically interacts with cGAS and promotes formation of large cGAS complexes, enhancing DNA binding of cGAS and its activation; G3BP1 deficiency leads to inefficient DNA binding by cGAS and inhibited cGAS-dependent IFN production. PMID:30510222 Nature immunology
2019 High cGAS-dependent IRF3 phosphorylation during mitotic arrest promotes apoptosis through transcription-independent alleviation of Bcl-xL-dependent suppression of mitochondrial outer membrane permeabilization; nucleosomes competitively inhibit DNA-dependent cGAS activation so cGAS-STING is not effectively activated during normal mitosis. PMID:31299200 Cell
2019 High STING activates autophagy through a TBK1- and interferon-independent mechanism upon cGAMP binding; STING translocates to the ERGIC and Golgi in a COP-II- and ARF GTPase-dependent manner, and STING-containing ERGIC serves as a membrane source for LC3 lipidation (autophagosome biogenesis) dependent on WIPI2 and ATG5. PMID:30842662 Nature
2020 High Cryo-EM structure of human cGAS bound to nucleosomes revealed that cGAS makes extensive contacts with the acidic patch of H2A-H2B and nucleosomal DNA; nucleosome binding locks cGAS into an inactive monomeric state through steric hindrance. Mutations to the cGAS-acidic patch interface abolished nucleosome-mediated inhibition in vitro and unleashed cGAS activity on genomic DNA in living cells. PMID:32911482 Nature
2020 High Cryo-EM structure (3.3 Å) of cGAS bound to nucleosome core particle showed cGAS uses two conserved arginines to anchor to the nucleosome acidic patch; this nucleosome-binding interface exclusively occupies the strong dsDNA-binding surface on cGAS and sterically prevents cGAS from oligomerizing into the active 2:2 cGAS-dsDNA state. PMID:32913000 Science
2020 Medium DNA-PK (DNA-PKcs) phosphorylates cGAS and suppresses its enzymatic activity; DNA-PK deficiency reduces cGAS phosphorylation and promotes antiviral innate immune responses. PMID:33273464 Nature communications
2021 High cGAS activity is selectively suppressed during mitosis by two parallel mechanisms: (1) hyperphosphorylation of the N-terminus by mitotic kinases including Aurora kinase B, which blocks chromatin sensing; and (2) prevention of oligomerization of chromatin-bound cGAS. Together these prevent autoimmune activation when cGAS contacts chromatin during mitosis. PMID:33542149 Science
2021 High TREX1 (ER-associated nuclease) inhibits cGAS activation at micronuclei by degrading micronuclear DNA upon micronuclear envelope rupture; the ER accesses ruptured micronuclei and enables TREX1 nucleolytic attack. TREX1 mutations that untether it from the ER disrupt localization to micronuclei and enhance cGAS activation. PMID:33476576 Molecular cell
2021 Medium cGAS functions as a micronucleophagy receptor: it accumulates in autophagic machinery and directly interacts with MAP1LC3B via a MAP1LC3-interacting region (LIR). This interaction is essential for LC3 recruitment to micronuclei and their clearance via selective autophagy, which dampens cGAMP production induced by genotoxic stress. PMID:33752561 Autophagy
2022 High Palmitoylation of cGAS at C474, catalyzed mainly by the palmitoyltransferase ZDHHC18, restricts cGAS enzymatic activity by reducing the interaction between cGAS and dsDNA and inhibiting cGAS dimerization; dsDNA promotes this palmitoylation modification. PMID:35438208 The EMBO journal
2022 Medium PRMT1 methylates cGAS at conserved Arg133, preventing cGAS dimerization and suppressing cGAS/STING signaling in cancer cells; PRMT1 ablation activates cGAS/STING-dependent DNA sensing and elevates type I and II interferon response genes. PMID:37193698 Nature communications
2022 High Cytoplasmic PARP1 (translocated via DNA-PK-mediated Thr594 phosphorylation) directly PARylates cGAS at Asp191, inhibiting its DNA-binding ability and antiviral immunity. PMID:35460603 Molecular cell
2022 Medium Cytoplasmic RNAs promote phase separation of cGAS in vitro and colocalize with phase-separated cGAS-dsDNA condensates in cells; RNAs enhance cGAS enzymatic activity when dsDNA concentration is low by promoting condensate formation. PMID:36382803 EMBO reports
2023 Medium cGAS is localized to the outer mitochondrial membrane in hepatocellular carcinoma cells, where it associates with DRP1 to facilitate DRP1 oligomerization; loss of cGAS or DRP1 oligomerization increases mitochondrial ROS and ferroptosis, inhibiting tumor growth. PMID:36864172 Cell research
2023 High ZBP1 stabilizes Z-form mtDNA and nucleates a cytosolic complex containing cGAS, RIPK1, and RIPK3 to sustain STAT1 phosphorylation and type I IFN signaling; cGAS cooperates with ZBP1 in detecting mitochondrial genome instability. PMID:37352855 Cell
2023 High Cytosolic DNA released from perturbed mitochondria elicits cGAS activity in old microglia; cGAS gain-of-function in microglia is sufficient to drive ageing-associated transcriptional states, neurodegeneration, and cognitive decline via STING. PMID:37532932 Nature
2023 Medium SIRT2 deacetylates G3BP1 at K257, K276, and K376, causing disassembly of the cGAS-G3BP1 complex, thereby inhibiting cGAS DNA binding and droplet formation and suppressing IFN production; SIRT2 deficiency or inhibition enhances cGAS-STING signaling. PMID:37870259 EMBO reports
2024 High The MRE11-RAD50-NBN complex displaces cGAS from nucleosome acidic-patch-mediated sequestration by binding to nucleosome fragments, enabling cGAS mobilization and activation by dsDNA; MRE11 is essential for cGAS activation in response to oncogenic stress, cytosolic dsDNA, and ionizing radiation, and MRE11-dependent cGAS activation promotes ZBP1-RIPK3-MLKL-mediated necroptosis. PMID:38200309 Nature
2024 High The CRL5-SPSB3 ubiquitin ligase complex degrades nuclear cGAS in cycling cells; SPSB3 is the substrate receptor that ligates ubiquitin onto nuclear cGAS via a conserved C-terminal Asn-Asn (NN) degron motif. Cryo-EM structure of nucleosome-bound cGAS in complex with SPSB3 revealed the structural basis. Interference with SPSB3-mediated nuclear cGAS degradation primes cells for type I IFN signaling. PMID:38418882 Nature
2024 High AARS2 associates with cGAS and mediates its lactylation (via AARS1/2 acting as lactyltransferases) at an N-terminal site, abolishing cGAS liquid-like phase separation and DNA sensing; a lactyl-resistant cGAS knock-in protects mice against innate immune evasion induced by high L-lactate. PMID:39322678 Nature
2024 Medium HERC5 catalyzes ISGylation of cGAS at K21, K187, K219, and K458; ISGylation promotes DNA-induced cGAS oligomerization and enhances cGAS enzymatic activity. USP18 removes ISGylation from cGAS. ISGylation deficiency attenuates IFN expression and antiviral defense. PMID:38421872 Cell reports
2020 Medium Cancer cells produce cGAMP that is transferred via gap junctions to tumor-associated dendritic cells and macrophages, which respond by producing type I IFN in situ; cancer-cell-intrinsic cGAS (but not STING) expression promotes CD8+ T cell infiltration and tumor immunogenicity. PMID:31665636 Cell reports

Citations