HST1

UniProt ID: P53685
Organism: Saccharomyces cerevisiae
Review Status: DRAFT
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Gene Description

HST1 encodes a nuclear NAD-dependent sirtuin deacetylase that is recruited by Sum1 and the tethering factor Rfm1 to selected chromosomal loci. Local histone deacetylation, prominently at H4K5, represses middle-sporulation and metabolic gene programs during vegetative growth and also supports efficient initiation at a subset of replication origins. Unlike its paralog Sir2, native Hst1 is a gene-specific chromatin regulator rather than a regional silencing factor at telomeres or silent mating-type loci.

Proposed New Ontology Terms

histone H4K5 deacetylase activity, NAD-dependent

Definition: Catalysis of the removal of an acetyl group from lysine 5 of histone H4 using NAD+ as a reactant, producing deacetylated histone, nicotinamide, and 2'-O-acetyl-ADP-ribose.

Justification: Current GO has an H4K5-specific term for the hydrolytic mechanism and several residue-specific NAD-dependent histone deacetylase terms, but no NAD-dependent H4K5 child of GO:0017136. Hst1-specific experiments identify H4K5 as its main histone H4 target.

Parent term: histone deacetylase activity, NAD-dependent

Supporting Evidence:

Existing Annotations Review

GO Term Evidence Action Reason
GO:0005634 nucleus
IBA
GO_REF:0000033
ACCEPT
Summary: Hst1 is a nuclear chromatin-associated sirtuin recruited to specific promoters and replication origins.
Reason: Nuclear localization and locus-specific chromatin association are supported by PMID:11711434 and PMID:29066473.
GO:0006974 DNA damage response
IBA
GO_REF:0000033
MARK AS OVER ANNOTATED
Summary: A DNA-damage-response role has not been demonstrated for Hst1 itself.
Reason: This IBA appears to transfer a broad Sir2-family genome-stability role without positive Hst1-specific evidence; Hst1's demonstrated functions are locus-specific deacetylation and transcriptional repression.
GO:0003714 transcription corepressor activity
IBA
GO_REF:0000033
ACCEPT
Summary: Hst1 provides catalytic repression within the Sum1-Rfm1-Hst1 complex.
Reason: Rfm1 recruits Hst1 to Sum1-bound promoters to repress middle-sporulation genes (PMID:12612074).
Supporting Evidence:
PMID:12612074
Rfm1 interacts with both Sum1 and Hst1 and is required for the Sum1-Hst1 interaction.
GO:0031509 subtelomeric heterochromatin formation
IBA
GO_REF:0000033
REMOVE
Summary: Native Hst1 is a gene-specific repressor, not a telomeric regional-silencing enzyme.
Reason: Hst1 and Sir2 have distinct cofactor-targeting specificities; PMID:17242192 assigns telomeric regional silencing to Sir2-Sir3-Sir4 and gene-specific repression to Hst1-Rfm1-Sum1. This IBA transfers the Sir2 role to Hst1.
Supporting Evidence:
PMID:17242192
Nevertheless, the two proteins promote two mechanistically distinct forms of gene repression.
GO:0032041 histone H3K14 deacetylase activity, NAD-dependent
IBA
GO_REF:0000033
MARK AS OVER ANNOTATED
Summary: Hst1 deacetylates promoter histones, but H3K14 specificity has not been demonstrated for Hst1 itself.
Reason: Hst1-specific chromatin studies identify H4K5 as the predominant affected residue; this residue-specific IBA overextends broader sirtuin evidence. The proposed NAD-dependent H4K5 term records the supported specificity.
Supporting Evidence:
PMID:18990212
This was consistent with the notion that H4 K5 was the main target of the histone deacetylase Hst1, whereas other histone H4 lysine residues were minor or no targets of Hst1.
GO:0046969 histone H3K9 deacetylase activity, NAD-dependent
IBA
GO_REF:0000033
MARK AS OVER ANNOTATED
Summary: Hst1 is an NAD-dependent histone deacetylase, but H3K9 specificity is not established for Hst1.
Reason: The H3K9 assignment derives from family transfer, whereas Hst1-specific experiments primarily implicate H4K5. The proposed NAD-dependent H4K5 term records the supported specificity.
Supporting Evidence:
PMID:18990212
This was consistent with the notion that H4 K5 was the main target of the histone deacetylase Hst1, whereas other histone H4 lysine residues were minor or no targets of Hst1.
GO:0046970 histone H4K16 deacetylase activity, NAD-dependent
IBA
GO_REF:0000033
MARK AS OVER ANNOTATED
Summary: H4K16 can be affected at selected Hst1-regulated origins, but it is not a general Hst1 substrate.
Reason: PMID:18990212 explicitly found H4K16 was not a general Hst1 target; H4K5 was the main residue affected. The proposed NAD-dependent H4K5 term records the supported specificity.
Supporting Evidence:
PMID:18990212
Similarly, our analysis indicated that H4 K16 was not a general target of deacetylation by Hst1.
GO:0000781 chromosome, telomeric region
IEA
GO_REF:0000108
REMOVE
Summary: Hst1 acts at selected nuclear loci but is not normally a telomere-associated silencing factor.
Reason: This GO_REF:0000108 IEA is derived mechanically from GO:0031509. PMID:17242192 instead assigns telomeric regional silencing to Sir2-Sir3-Sir4 and gene-specific repression to Hst1-Rfm1-Sum1.
Supporting Evidence:
PMID:17242192
Hst1 interacts with Rfm1 and Sum1 to repress the transcription of specific middle-sporulation genes.
GO:0000785 chromatin
IEA
GO_REF:0000117
ACCEPT
Summary: Hst1 is recruited to chromatin at Sum1-regulated promoters and selected replication origins.
Reason: Chromatin association and locus-specific loss of Hst1 binding are directly demonstrated in PMID:29066473.
GO:0005634 nucleus
IEA
GO_REF:0000044
ACCEPT
Summary: Hst1 localizes to the nucleus, where it acts on promoter chromatin.
Reason: Nuclear localization is experimentally supported and coherent with its chromatin-targeted repression.
GO:0017136 histone deacetylase activity, NAD-dependent
IEA
GO_REF:0000117
ACCEPT
Summary: NAD-dependent histone deacetylation is Hst1's core catalytic activity.
Reason: Direct genetic and biochemical studies establish Hst1-dependent histone deacetylation (PMID:11313477; PMID:12972620).
Supporting Evidence:
PMID:12972620
The NAD(+)-dependent deacetylase activity of Hst1p represses de novo NAD(+) biosynthesis genes in the absence of new protein synthesis, suggesting a direct effect.
GO:0030466 silent mating-type cassette heterochromatin formation
IEA
GO_REF:0000117
MARK AS OVER ANNOTATED
Summary: Hst1 can support HMR silencing in engineered Sum1-1 or sensitized backgrounds, but this is not its normal physiological role.
Reason: The unqualified IEA obscures that Hst1-dependent mating-type silencing is conditional on altered targeting rather than native regional silencing.
Supporting Evidence:
PMID:11313477
Sum1-1 requires the Sir2 homolog, Hst1, for silencing and most probably requires the NAD(+)-dependent deacetylase activity of this protein.
GO:0031981 nuclear lumen
IEA
GO_REF:0000117
KEEP AS NON CORE
Summary: Nuclear lumen is a correct broad localization but less informative than nucleus/chromatin.
Reason: The location is compatible with experimental nuclear localization but does not describe the locus-targeted activity.
GO:0034979 NAD-dependent protein lysine deacetylase activity
IEA
GO_REF:0000120
ACCEPT
Summary: Hst1 catalyzes NAD-dependent lysine deacetylation of protein substrates, physiologically including promoter histones.
Reason: This activity-level term accurately captures the sirtuin reaction without overcommitting to an unsupported histone residue.
Supporting Evidence:
PMID:12972620
The NAD(+)-dependent deacetylase activity of Hst1p represses de novo NAD(+) biosynthesis genes in the absence of new protein synthesis, suggesting a direct effect.
GO:0045892 negative regulation of DNA-templated transcription
IEA
GO_REF:0000108
ACCEPT
Summary: Hst1 represses specific RNA polymerase II transcription programs through promoter histone deacetylation.
Reason: Middle-sporulation, NAD-biosynthesis, and thiamine-biosynthesis genes are directly repressed by Hst1. The NAD-biosynthesis program is represented more specifically by existing GO:1905013, negative regulation of 'de novo' NAD biosynthetic process from L-tryptophan.
Supporting Evidence:
PMID:10562556
SUM1 and HST1, genes previously associated with transcriptional silencing, are required for MSE-mediated repression.
GO:0045910 negative regulation of DNA recombination
IEA
GO_REF:0000117
MARK AS OVER ANNOTATED
Summary: A broad negative-regulation-of-recombination role is not supported for Hst1.
Reason: The directly tested hst1 disruption had no rDNA recombination phenotype. The separate mitotic-recombination IMP remains UNDECIDED pending its inaccessible full-text evidence, but it does not justify this broad electronic assignment.
Supporting Evidence:
PMID:8810037
Disruption of HST1 has shown no phenotype with respect to mechanisms in which SIR2 has a role, namely, regional silencing of HML alpha, or in rDNA recombination.
GO:0070403 NAD+ binding
IEA
GO_REF:0000002
ACCEPT
Summary: NAD+ binding is intrinsic to the Hst1 sirtuin catalytic cycle.
Reason: Hst1 consumes NAD+ during deacetylation, and PMID:12972620 directly reports its comparatively low NAD+ affinity.
Supporting Evidence:
PMID:12972620
In vitro experiments demonstrate that Hst1p has relatively low affinity toward NAD(+) in comparison to other NAD(+)-dependent enzymes.
GO:0005515 protein binding
IPI
PMID:12612074
Rfm1, a novel tethering factor required to recruit the Hst1 ...
MARK AS OVER ANNOTATED
Summary: The Rfm1-Hst1 interaction recruits Hst1 to Sum1-bound promoters, but generic protein binding is uninformative.
Reason: PMID:12612074 supports a specific tethering interaction that GO:0005515 fails to represent.
GO:0005515 protein binding
IPI
PMID:16429126
Proteome survey reveals modularity of the yeast cell machine...
MARK AS OVER ANNOTATED
Summary: A high-throughput interaction does not define Hst1's molecular function.
Reason: Generic protein binding should not replace the specific NAD-dependent deacetylase and corepressor activities.
GO:0005515 protein binding
IPI
PMID:37968396
The social and structural architecture of the yeast protein ...
MARK AS OVER ANNOTATED
Summary: Proteome-scale interaction evidence does not justify generic protein binding as an informative function.
Reason: Hst1's mechanistic partners and catalytic activity are already represented more specifically.
GO:0005634 nucleus
IDA
PMID:11711434
The S. cerevisiae SET3 complex includes two histone deacetyl...
ACCEPT
Summary: Hst1 is experimentally localized to the nucleus.
Reason: The Set3C study and independent localization data support nuclear localization.
GO:0006974 DNA damage response
NAS
PMID:11711434
The S. cerevisiae SET3 complex includes two histone deacetyl...
MARK AS OVER ANNOTATED
Summary: PMID:11711434 establishes Hst1-containing deacetylase complexes but not a direct Hst1 DNA-damage-response role.
Reason: This ComplexPortal-associated NAS extends chromatin-complex membership to a process not demonstrated for Hst1 in the cited paper.
GO:0009267 cellular response to starvation
NAS
PMID:11711434
The S. cerevisiae SET3 complex includes two histone deacetyl...
KEEP AS NON CORE
Summary: Nutrient state modulates Hst1-regulated sporulation and metabolic transcription programs.
Reason: Starvation response is biologically relevant to relief of sporulation repression but is downstream of Hst1's catalytic core function.
GO:0034967 Set3 complex
IPI
PMID:11711434
The S. cerevisiae SET3 complex includes two histone deacetyl...
KEEP AS NON CORE
Summary: Hst1 is an experimentally identified Set3C subunit, although it is largely dispensable for Set3C repression.
Reason: PMID:11711434 places Hst1 in Set3C but identifies the Sum1-Rfm1-Hst1 complex as the stronger Hst1-dependent context.
Supporting Evidence:
PMID:11711434
The S. cerevisiae SET3 complex includes two histone deacetylases, Hos2 and Hst1, and is a meiotic-specific repressor of the sporulation gene program.
GO:0045835 negative regulation of meiotic nuclear division
IDA
PMID:11711434
The S. cerevisiae SET3 complex includes two histone deacetyl...
MARK AS OVER ANNOTATED
Summary: Hst1 represses middle-sporulation genes during vegetative growth, but direct negative regulation of meiotic nuclear division overstates that transcriptional role.
Reason: The cited Set3C study reports that Hst1 is not required for meiotic repression by Set3C; the supported Hst1 role is gene-specific repression through Sum1-Rfm1.
Supporting Evidence:
PMID:11711434
However, Hst1 is not required for meiotic repression by Set3C, thus implying that Set3C (-Hst1) and not Hst1-Sum1, is the meiotic-specific repressor.
GO:0000118 histone deacetylase complex
IPI
PMID:11711434
The S. cerevisiae SET3 complex includes two histone deacetyl...
ACCEPT
Summary: Hst1 is the catalytic subunit of promoter-targeted histone deacetylase complexes.
Reason: Physical association with Sum1-Rfm1 and Set3C supports membership in histone deacetylase complexes.
GO:0006357 regulation of transcription by RNA polymerase II
NAS
PMID:12612074
Rfm1, a novel tethering factor required to recruit the Hst1 ...
ACCEPT
Summary: Hst1 regulates selected RNA polymerase II genes through local chromatin deacetylation.
Reason: PMID:12612074 directly links Sum1-Rfm1 recruitment of Hst1 to repression of middle-sporulation genes.
Supporting Evidence:
PMID:10562556
SUM1 and HST1, genes previously associated with transcriptional silencing, are required for MSE-mediated repression.
GO:0030174 regulation of DNA-templated DNA replication initiation
NAS
PMID:18990212
Control of replication initiation by the Sum1/Rfm1/Hst1 hist...
KEEP AS NON CORE
Summary: Hst1 promotes efficient initiation at a subset of Sum1-bound replication origins through histone deacetylation.
Reason: PMID:18990212 provides direct Hst1-specific evidence, but origin control is secondary to promoter repression.
Supporting Evidence:
PMID:18990212
We identified seven ARS elements whose initiation capacity depended on Sum1 and Hst1.
GO:0043937 regulation of sporulation
NAS
PMID:12612074
Rfm1, a novel tethering factor required to recruit the Hst1 ...
ACCEPT
Summary: Hst1 represses middle-sporulation genes during vegetative growth and thereby regulates the sporulation program.
Reason: Sum1-Rfm1 recruits Hst1 to these promoters, and loss of the complex derepresses the program (PMID:12612074).
Supporting Evidence:
PMID:10562556
SUM1 and HST1, genes previously associated with transcriptional silencing, are required for MSE-mediated repression.
GO:0008270 zinc ion binding
RCA
PMID:30358795
The cellular economy of the Saccharomyces cerevisiae zinc pr...
ACCEPT
Summary: Hst1 contains the conserved structural zinc-binding subdomain of sirtuins.
Reason: Zinc binding is a conserved structural feature of the sirtuin catalytic domain and is consistent with the Hst1 sequence/domain annotation.
GO:0017136 histone deacetylase activity, NAD-dependent
IDA
PMID:11313477
A novel form of transcriptional silencing by Sum1-1 requires...
ACCEPT
Summary: Hst1-dependent NAD-dependent histone deacetylase activity is required for engineered Sum1-1 silencing.
Reason: PMID:11313477 directly tested the requirement for Hst1 in this conditional silencing system.
GO:0017136 histone deacetylase activity, NAD-dependent
IDA
PMID:11711434
The S. cerevisiae SET3 complex includes two histone deacetyl...
ACCEPT
Summary: Hst1 is one of the histone deacetylases identified in Set3C.
Reason: PMID:11711434 experimentally identifies Hst1 in the complex and supports NAD-dependent histone deacetylase activity.
GO:0030466 silent mating-type cassette heterochromatin formation
IGI
PMID:27185881
Determinants of Sir2-Mediated, Silent Chromatin Cohesion.
UNDECIDED
Summary: The study concerns Sir2-mediated silent-chromatin cohesion; the cached abstract is insufficient to verify the Hst1 genetic interaction.
Reason: Preserve the curator's experimental IGI annotation pending access to the full supporting evidence; do not infer misattribution from an abstract centered on Sir2.
GO:0030466 silent mating-type cassette heterochromatin formation
IMP
PMID:11313477
A novel form of transcriptional silencing by Sum1-1 requires...
KEEP AS NON CORE
Summary: Hst1 is required for HMR silencing when recruited by the gain-of-function Sum1-1 protein.
Reason: PMID:11313477 supports the annotation in this engineered context, but native Hst1 does not normally perform regional mating-type silencing.
GO:0030466 silent mating-type cassette heterochromatin formation
IGI
PMID:11313477
A novel form of transcriptional silencing by Sum1-1 requires...
KEEP AS NON CORE
Summary: Genetic evidence supports Hst1-dependent Sum1-1 silencing at HMR.
Reason: Retain the experimentally curated interaction while making the non-native targeting context explicit.
GO:0034967 Set3 complex
IDA
PMID:11711434
The S. cerevisiae SET3 complex includes two histone deacetyl...
KEEP AS NON CORE
Summary: Hst1 is an experimentally identified Set3C component.
Reason: Set3C membership is real, but Hst1 is not essential for the complex's meiotic repression and its main complex is Sum1-Rfm1-Hst1.
GO:0045950 negative regulation of mitotic recombination
IMP
PMID:16051752
HST2 mediates SIR2-independent life-span extension by calori...
UNDECIDED
Summary: The cached abstract focuses on Hst2-mediated lifespan regulation and does not expose the experiment supporting Hst1-dependent recombination control.
Reason: The IMP annotation should not be overruled without the relevant full-text evidence; retain for curator follow-up.
GO:0070623 regulation of thiamine biosynthetic process
IMP
PMID:20439498
Thiamine biosynthesis in Saccharomyces cerevisiae is regulat...
KEEP AS NON CORE
Summary: Hst1 links NAD+ availability to basal repression of thiamine biosynthesis genes.
Reason: PMID:20439498 directly supports this extra program, but it is one target set of the broader Hst1 promoter-repression mechanism.
Supporting Evidence:
PMID:20439498
We have determined that multiple thiamine ( THI ) genes in Saccharomyces cerevisiae are also regulated by the intracellular NAD + concentration via the NAD + -dependent histone deacetylase (HDAC) Hst1 and, to a lesser extent, Sir2.

Core Functions

Hst1 is the NAD-dependent histone deacetylase of the Sum1-Rfm1-Hst1 transcriptional repressor. Sum1 specifies target loci and Rfm1 recruits Hst1, whose local deacetylation of promoter chromatin, predominantly H4K5, represses middle-sporulation and selected metabolic genes during vegetative growth.

Supporting Evidence:
  • PMID:12612074
    Rfm1 interacts with both Sum1 and Hst1 and is required for the Sum1-Hst1 interaction.
  • PMID:29066473
    Set1 appeared to promote the association of the sequence-specific DNA binding protein Sum1 and the HDAC Hst1 with middle sporulation genes to maintain deacetylation, primarily at H4K5, and gene repression.

References

Gene Ontology annotation through association of InterPro records with GO terms
Annotation inferences using phylogenetic trees
Gene Ontology annotation based on UniProtKB/Swiss-Prot Subcellular Location vocabulary mapping, accompanied by conservative changes to GO terms applied by UniProt
Automatic assignment of GO terms using logical inference, based on on inter-ontology links
Electronic Gene Ontology annotations created by ARBA machine learning models
Combined Automated Annotation using Multiple IEA Methods
file:yeast/HST1/HST1-deep-research-openscientist.md
OpenScientist GO-focused literature synthesis for yeast HST1
HST1, a new member of the SIR2 family of genes.
Sum1 and Hst1 repress middle sporulation-specific gene expression during mitosis in Saccharomyces cerevisiae.
NAD+-dependent deacetylase Hst1p controls biosynthesis and cellular NAD+ levels in Saccharomyces cerevisiae.
Swapping the gene-specific and regional silencing specificities of the Hst1 and Sir2 histone deacetylases.
Repression of Middle Sporulation Genes in Saccharomyces cerevisiae by the Sum1-Rfm1-Hst1 Complex Is Maintained by Set1 and H3K4 Methylation.
A novel form of transcriptional silencing by Sum1-1 requires Hst1 and the origin recognition complex.
The S. cerevisiae SET3 complex includes two histone deacetylases, Hos2 and Hst1, and is a meiotic-specific repressor of the sporulation gene program.
Rfm1, a novel tethering factor required to recruit the Hst1 histone deacetylase for repression of middle sporulation genes.
HST2 mediates SIR2-independent life-span extension by calorie restriction.
Proteome survey reveals modularity of the yeast cell machinery.
Control of replication initiation by the Sum1/Rfm1/Hst1 histone deacetylase.
Thiamine biosynthesis in Saccharomyces cerevisiae is regulated by the NAD+-dependent histone deacetylase Hst1.
Determinants of Sir2-Mediated, Silent Chromatin Cohesion.
The cellular economy of the Saccharomyces cerevisiae zinc proteome.
The social and structural architecture of the yeast protein interactome.

Suggested Questions for Experts

Q: Which endogenous Hst1 target proteins, if any, are deacetylated outside chromatin, and do such substrates account for the secondary DNA-damage and recombination phenotypes assigned to the Sir2 family?

Q: How does the Sum1-Rfm1-Hst1 complex choose between middle-sporulation, NAD-biosynthesis, thiamine-biosynthesis, and replication-origin targets as nutrient state and intracellular NAD+ change?

Suggested Experiments

Experiment: Combine acute Hst1 depletion with calibrated residue-specific histone acetylation profiling and Hst1/Sum1 ChIP-seq across vegetative, NAD-limited, and sporulation-inducing conditions, then test catalytic-dead Hst1 rescue at directly bound loci.

Hypothesis: H4K5 is the dominant physiological histone substrate of promoter-bound Hst1, whereas the H3K9, H3K14, and H4K16 residue-specific IBA assignments are not broadly applicable to native Hst1 targets.

Type: acute depletion, quantitative histone acetyl-proteomics, and ChIP-seq

Deep Research

OpenScientist

(HST1-deep-research-openscientist.md)
HST1 (YOL068C, UniProt P53685): A Nuclear NAD⁺-Dependent Sirtuin Deacetylase and Gene-Specific Repressor in *Saccharomyces cerevisiae* OpenScientist openscientist-autonomous 22 citations 2 artifacts 2026-08-12T09:03:57.628853

HST1 (YOL068C, UniProt P53685): A Nuclear NAD⁺-Dependent Sirtuin Deacetylase and Gene-Specific Repressor in Saccharomyces cerevisiae

Summary

HST1 (Homologous to Sir Two 1; systematic name YOL068C; UniProt P53685) encodes a nuclear, chromatin-associated NAD⁺-dependent protein/histone lysine deacetylase of the Sir2 (sirtuin) family, classified as EC 2.3.1.286 and belonging to the sirtuin Class I subfamily. The enzyme removes acetyl groups from acetyl-lysine residues on nucleosomal histone tails (histone H4, including H4K5 and H4K16; histone H3 at K9/K14) using an obligate, stoichiometric consumption of NAD⁺. For each lysine deacetylated, one molecule of NAD⁺ is cleaved, generating three products: the deacetylated lysine, nicotinamide, and the novel metabolite 2β€²-O-acetyl-ADP-ribose (OAADPr). This catalytic chemistry β€” coupling deacetylation to NAD⁺ hydrolysis β€” is the defining and mechanistically conserved feature of the entire sirtuin family, and it distinguishes sirtuins (Class III HDACs) from the zinc-dependent Class I/II histone deacetylases.

The primary physiological function of Hst1 is gene-specific transcriptional repression, not the regional heterochromatic silencing performed by its close paralog Sir2. Hst1 is the catalytic engine of the Sum1–Rfm1–Hst1 complex, in which the DNA-binding protein Sum1 recognizes Middle Sporulation Elements (MSEs) in target promoters, the tethering factor Rfm1 bridges Sum1 to Hst1, and Hst1 then deacetylates promoter nucleosomes to condense local chromatin and silence transcription. Through this complex, Hst1 represses middle-sporulation/meiotic genes (including the master meiotic activator NDT80, as well as IME2 and SMA2/mORC1) during vegetative (mitotic) growth. This repression is gene-specific β€” it does not spread to neighboring genes β€” and it is relieved during meiosis when the activator Ndt80 outcompetes Sum1 for MSE occupancy. A second distinct regulatory role identifies Hst1 as an NAD⁺ sensor: because it has relatively low affinity for NAD⁺, its deacetylase activity (and hence its repression of the de novo NAD⁺ biosynthesis "BNA" genes) declines when cellular NAD⁺ falls, forming a feedback loop that homeostatically regulates NAD⁺ biosynthesis.

Hst1 operates in the nucleus, on chromatin, at specific gene promoters. Although Hst1 is 71% identical to Sir2 and shares a near-identical catalytic core (a large Rossmann-fold NAD⁺-binding domain plus a small zinc-binding subdomain), the two enzymes are functionally divergent: Hst1's endogenous role is gene-specific promoter repression via Sum1/Rfm1, whereas Sir2's is regional silencing via Sir3/Sir4. This divergence arises from distinct cofactor/targeting specificities rather than differences in catalytic chemistry β€” a conclusion supported by domain-swap experiments. Only when artificially targeted (e.g., in the SUM1-1 gain-of-function background via the origin recognition complex) can Hst1 substitute for Sir2 in HMR silencing. The gene symbol is not ambiguous in this context: all literature reviewed corresponds precisely to the S. cerevisiae sirtuin HST1.


Key Findings

Finding 1: Hst1 is an NAD⁺-dependent Class III histone/protein deacetylase (sirtuin) with a defined catalytic mechanism

Hst1 (YOL068C) is one of four Sir2 homologs (Hst1–Hst4) in budding yeast and is a phylogenetically conserved NAD⁺-dependent protein deacetylase. The sirtuins are described as "a phylogenetically conserved family of NAD(+)-dependent protein deacetylases that consume one molecule of NAD(+) for every deacetylated lysine side chain" (PMID: 24164855). This one-to-one stoichiometry of NAD⁺ consumption to lysine deacetylation is the biochemical signature of the family and the reason Hst1's activity is inherently coupled to the cell's metabolic state.

The reaction catalyzed produces three products. Sir2-family enzymes are "NAD(+)-dependent histone/protein deacetylases that tightly couple the hydrolysis of NAD(+) and the deacetylation of an acetylated substrate to form nicotinamide, the deacetylated product, and the novel metabolite O-acetyl-ADP-ribose (OAADPR)" (PMID: 15274642). Mechanistic studies establish a sequential ternary-complex mechanism: nicotinamide is cleaved from NAD⁺ first, forming a covalent Ξ±-1β€²-O-alkylamidate intermediate, after which the acetyl group is transferred to ADP-ribose. Direct evidence for this pathway comes from work "providing direct evidence for the formation of a covalent alpha-1'-O-alkylamidate" (PMID: 16388603), which also implicates a conserved catalytic histidine (His135 in the paralog Hst2) acting as a general base that activates the ribose 2β€²-OH. Because nicotinamide is both a reaction product and a feedback inhibitor, the mechanism itself provides a natural regulatory handle (see Finding 8).

This is the assigned enzymatic identity of Hst1: EC 2.3.1.286, a NAD-dependent protein deacetylase of the sirtuin Class I subfamily.

Finding 2: Hst1's primary function is gene-specific repression of middle-sporulation genes as the catalytic subunit of the Sum1–Rfm1–Hst1 complex

The central physiological role of Hst1 is to serve as the catalytic subunit of a promoter-targeted repressor complex. Hst1 does not itself bind DNA; instead it is recruited to specific promoters by the sequence-specific DNA-binding protein Sum1, with the bridging/tethering factor Rfm1 connecting the two. The architecture was defined by the discovery that "Rfm1 interacts with both Sum1 and Hst1 and is required for the Sum1-Hst1 interaction" (PMID: 12612074). Rfm1 is required both for the physical Sum1–Hst1 interaction and for repression of the Hst1-dependent subset of middle-sporulation genes.

The functional output is described as the cooperation of "the NAD(+)-dependent histone deacetylase Hst1 and the DNA-binding protein Sum1 for vegetative repression of many middle sporulation genes" (PMID: 12612074). Mechanistically, once recruited, Hst1 deacetylates promoter nucleosomes, condensing local chromatin and blocking transcription of genes needed for meiotic progression and spore formation during vegetative growth. A later study confirmed that "Hst1 interacts with Rfm1 and Sum1 to repress the transcription of specific middle-sporulation genes" (PMID: 17242192).

Critically, the difference between Hst1 (gene-specific repression) and Sir2 (regional silencing) is not a difference in enzymatic chemistry. Domain-swap and chimera experiments showed that "the differences in the silencing and repression functions of Sir2 and Hst1 may not be due to differences in enzymatic activities of the proteins but rather may be the result of distinct cofactor specificities" (PMID: 17242192). Gene-specific repression requires the Rfm1 + Sum1 cofactors, whereas Sir2's regional silencing requires Sir3 + Sir4; specificity is set by non-conserved N-terminal sequences and a small number of core residues, not by catalysis.

Finding 3: Hst1 is an NAD⁺ sensor that represses de novo NAD⁺ biosynthesis genes

Beyond its role in meiotic-gene repression, Hst1 functions as a metabolic sensor that closes a feedback loop on NAD⁺ biosynthesis. Transcript-array analyses demonstrated that "the NAD(+)-dependent deacetylase activity of Hst1p represses de novo NAD(+) biosynthesis genes in the absence of new protein synthesis, suggesting a direct effect" (PMID: 12972620). The salvage-pathway genes are unaffected, and Sum1 occupies the promoters of the inducible de novo (BNA) biosynthesis genes, tying this repression to the same Sum1-targeting logic as the meiotic genes.

This established "a critical role of the NAD(+)-dependent deacetylase Hst1p as a sensor of NAD(+) levels and regulator of NAD(+) biosynthesis" (PMID: 12972620). The logic is elegant: because Hst1 has relatively low affinity for NAD⁺ compared with other sirtuins, its activity is sensitive to falling NAD⁺ concentrations. When NAD⁺ is plentiful, Hst1 is active and represses the biosynthesis genes; when NAD⁺ drops, Hst1 activity declines, de-repressing the de novo pathway to restore NAD⁺. Consistent with this, "the removal of HST1-mediated repression of the NAD(+) de novo biosynthesis pathway leads to increased cellular NAD(+) levels" (PMID: 12972620). A subsequent study further linked Hst1 (together with the copper-sensing transcription factor Mac1 and nicotinic acid) to the regulation of NAD biosynthesis genes (PMID: 30760525).

Finding 4: Hst1 can substitute for Sir2 in HMR silencing when artificially targeted, and contributes to genome stability

Although Hst1 does not natively perform regional silencing, its catalytic capacity to silence chromatin can be revealed by artificial targeting. In the SUM1-1 gain-of-function background, Sir-independent silencing at the HMR locus requires Hst1: "Sum1-1 requires the Sir2 homolog, Hst1, for silencing and most probably requires the NAD(+)-dependent deacetylase activity of this protein" (PMID: 11313477). In this context, the mutant Sum1-1 protein binds the origin recognition complex (ORC) at HMR and recruits Hst1, which then "deacetylates histones or other chromatin-associated proteins to cause chromatin condensation and transcriptional silencing" (PMID: 11313477).

Evolutionary analyses reinforce that Hst1 is a functionally central and retained sirtuin. In the CTG-clade Candida yeasts, "HST1 has been consistently retained throughout the clade, whereas SIR2 is only present in a subset of species" (PMID: 27543294), and the retained HST1 paralog can regain ancestral silencing functions β€” underscoring that the near-identical catalytic core is readily repurposed by changing its targeting partners. Genome-wide nicotinamide sensitivity screens further found that genome-stability pathways, including sister-chromatid cohesion, are especially vulnerable to loss of sirtuin activity (PMID: 26646153).

Finding 5: Repression is gene-specific via MSE promoter elements and is relieved by Ndt80 competition during meiosis

The gene-specificity of Hst1/Sum1 repression is encoded in Middle Sporulation Elements (MSEs) in target promoters. "SUM1 and HST1, genes previously associated with transcriptional silencing, are required for MSE-mediated repression. Sum1 binds specifically in vitro to MSEs that function as strong repressor sites in vivo. Repression by Sum1 is gene specific and does not extend to neighboring genes" (PMID: 10562556). This non-spreading, promoter-local character sharply distinguishes Hst1-mediated repression from Sir2-mediated heterochromatin, which spreads across kilobases.

The switch from repression to activation during meiosis is governed by direct competition between the repressor Sum1 and the activator Ndt80 for the same DNA elements: "Sum1 and Ndt80 compete for binding to MSEs and that small changes in the sequence of an MSE can yield large differences in which protein is bound" (PMID: 12832469). As cells enter middle meiosis, Ndt80 accumulates and displaces the Sum1–Rfm1–Hst1 repressor, de-repressing the middle-sporulation gene program. Target genes include the master meiotic regulators NDT80, IME2, and the SMA2/mORC1 locus (PMID: 27362276).

Finding 6: HST1 is 71% identical to SIR2 but, on its own, does not perform Sir2's regional silencing or rDNA functions

HST1 was originally identified as a SIR2-related gene, defining the HST (Homologous to Sir Two) family. It is "very closely related to SIR2, showing 71% sequence identity over 84% of its length" (PMID: 8810037). Despite this near-identity in the catalytic core, the endogenous roles diverge: "Disruption of HST1 has shown no phenotype with respect to mechanisms in which SIR2 has a role, namely, regional silencing of HML alpha, or in rDNA recombination" (PMID: 8810037). This is a key negative result: it establishes that Hst1's native function is distinct from Sir2's heterochromatin/rDNA maintenance, and that Hst1's silencing capacity is latent, revealed only when the enzyme is redirected by alternative targeting cofactors.

Finding 7: Structural architecture and localization β€” a nuclear, chromatin-associated sirtuin with a Rossmann-fold NAD⁺ domain and a small Zn-binding subdomain

The structural fold of Hst1 is inferred with high confidence from its close paralog Hst2, whose full-length crystal structure was solved. That structure revealed "a central catalytic core domain fold that is characteristic of the other Sir2 homologs, and C- and N-terminal extensions that interact with the NAD(+) and acetyl-lysine substrate-binding sites" (PMID: 14502267). The catalytic core is bipartite: a large Rossmann-fold domain that binds NAD⁺ (corresponding to InterPro IPR029035, DHS-like NAD/FAD-binding) and a smaller zinc-binding subdomain (IPR026591). A related sirtuin structure confirms "the characteristic small zinc-binding domain, and the larger Rossmann-fold domain involved in NAD+-binding interactions" (PMID: 29543820). The acetyl-lysine substrate binds in a cleft/hydrophobic tunnel between the two domains, and the sequence-divergent N- and C-terminal extensions provide autoregulatory modulation of substrate and cofactor binding β€” the structural basis for the cofactor/targeting specificity that distinguishes Hst1 from Sir2.

Functionally, Hst1 acts in the nucleus, on chromatin. Loss or mislocalization of the Sum1–Hst1 machinery causes "loss of the DNA-binding transcriptional regulator Sum1 and the associated histone deacetylase Hst1 from chromatin in a locus-specific manner. This is linked to increased H4K5ac at these loci" (PMID: 29066473). This directly demonstrates that Hst1 operates at specific chromatin loci and that its removal raises local histone acetylation β€” pinning down both its subcellular location (nuclear chromatin) and its substrate (nucleosomal histone tails).

Finding 8: Hst1 activity is tuned by NAD⁺ salvage (Pnc1/nicotinamide) and it is a shared subunit of two repressive complexes

Hst1 activity is regulated post-translationally by nicotinamide (NAM), the reaction product that acts as a physiological sirtuin inhibitor. The nicotinamidase Pnc1 clears NAM, relieving inhibition: "PNC1 overexpression suppresses the inhibitory effect of exogenously added NAM on silencing, life span, and Hst1-mediated transcriptional repression" (PMID: 14729974). Because PNC1 is stress-inducible, this links Hst1-dependent repression to environmental and metabolic stress signals.

Hst1 is also a shared subunit of a second repressive assembly, the Set3 complex (Set3C). "Set3 forms a single complex, Set3C, with Snt1, YIL112w, Sif2, Cpr1, and two putative histone deacetylases, Hos2 and NAD-dependent Hst1" (PMID: 11711434). Set3C thereby contains both NAD-dependent (Hst1) and NAD-independent (the Class I HDAC Hos2) deacetylase activities and represses early/middle sporulation genes such as IME2 and NDT80. Importantly, the same study confirms that "Hst1 is also present in a complex with Sum1, supporting previous characterizations of Hst1 and Sum1 as repressors of middle sporulation genes during vegetative growth" (PMID: 11711434). Because Hst1 is largely dispensable for Set3C's meiotic repression, the Sum1–Rfm1–Hst1 complex is regarded as the primary Hst1-dependent repressor.

Finding 9: Substrate specificity β€” nucleosomal histone lysines at target promoters

Hst1's characterized physiological substrates are the acetyl-lysines of N-terminal histone tails at repressed promoters. The yeast Sir2 family deacetylates specific histone lysines: "yeast and mouse Sir2 proteins are nicotinamide adenine dinucleotide (NAD)-dependent histone deacetylases, which deacetylate lysines 9 and 14 of H3 and specifically lysine 16 of H4" (PMID: 10693811). Structural work captured the Hst1 paralog Hst2 "in complex with its acetyl-lysine 16 histone H4 substrate" (PMID: 17289592), defining H4K16ac as a canonical family substrate.

For Hst1 specifically, in vivo evidence comes from the observation that loss of Sum1/Hst1 targeting produces "increased H4K5ac at these loci and aberrant middle gene expression" (PMID: 29066473), identifying nucleosomal histone H4 tail lysines (notably H4K5) as in vivo substrates at Hst1-repressed promoters. In vitro, sirtuins including this family can also accept longer acyl-lysine substrates (propionyl-, butyryl-lysine) (PMID: 17951578), and can deacetylate non-histone proteins β€” but Hst1's physiologically documented substrates are promoter nucleosomal histones. Its relatively low NAD⁺ affinity (PMID: 12972620) tunes its output to cellular NAD⁺ levels.


Mechanistic Model / Interpretation

Hst1 is best understood as a targeted, metabolically-gated chromatin repressor. It integrates three inputs β€” DNA sequence (via Sum1/MSE), cellular NAD⁺ level, and nicotinamide/stress signals β€” to control the timing of the meiotic gene program and NAD⁺ biosynthesis.

The core catalytic cycle

   Acetyl-Lys(histone) + NAD⁺
      β”‚
      β–Ό   [Hst1 catalytic core: Rossmann fold + Zn subdomain]
   Step 1: nicotinamide cleavage β†’ Ξ±-1β€²-O-alkylamidate intermediate
      β”‚
   Step 2: acetyl transfer to ADP-ribose (His as general base)
      β–Ό
   Deacetylated-Lys(histone) + Nicotinamide + 2β€²-O-acetyl-ADP-ribose (OAADPr)

The Sum1–Rfm1–Hst1 targeting and repression module

MSE promoter element
   ────────■────────────────────────  (target gene, e.g. NDT80, IME2, SMA2, BNA genes)
   β”‚
 [Sum1]  ── DNA-binding, sequence-specific
   β”‚
 [Rfm1]  ── tethering/bridging factor
   β”‚
 [Hst1]  ── NAD⁺-dependent deacetylase (catalytic subunit)
   β”‚
   β–Ό
   Deacetylation of H4K5/H4K16 (H3K9/K14) on promoter nucleosomes
   β”‚
   β–Ό
   Local chromatin condensation β†’ GENE-SPECIFIC REPRESSION (non-spreading)

Developmental switch during meiosis

   Vegetative growth:   Sum1–Rfm1–Hst1  bound at MSE  β†’ genes OFF
                     β”‚
          Meiosis: Ndt80 accumulates
                     β”‚  (competes for MSE)
                     β–Ό
   Middle meiosis:      Ndt80 bound at MSE            β†’ genes ON

Comparison: Hst1 vs. its paralog Sir2

Property Hst1 Sir2
Catalytic activity NAD⁺-dependent deacetylase (EC 2.3.1.286) NAD⁺-dependent deacetylase
Sequence identity β€” 71% identical to Hst1 over 84% of length
Targeting cofactors Sum1 + Rfm1 (also Set3C) Sir3 + Sir4
Mode of repression Gene-specific, promoter-local, non-spreading Regional heterochromatin, spreads
Native targets Middle-sporulation genes; de novo NAD⁺ (BNA) genes HM loci, telomeres, rDNA
NAD⁺ affinity Relatively low (metabolic sensor) Higher
Basis of divergence Cofactor/targeting specificity, not catalysis Cofactor/targeting specificity

Metabolic feedback (NAD⁺ sensing)

   High NAD⁺ ──► Hst1 active ──► BNA (de novo) genes repressed ──► NAD⁺ held in check
       β–²                                                                 β”‚
       └──────────── Low NAD⁺ ──► Hst1 inactive ──► BNA de-repressed β”€β”€β”€β”€β”˜
     (low NAD⁺ affinity makes Hst1 the sensor)

   Nicotinamide (NAM, a product) inhibits Hst1;  Pnc1 clears NAM (stress-induced) β†’ relieves inhibition

Taken together, these modules explain why Hst1 is specialized as a precise developmental and metabolic switch rather than a bulk chromatin silencer: its DNA targeting is delegated to Sum1/Rfm1, its catalysis is throttled by NAD⁺ availability and nicotinamide, and its low NAD⁺ affinity makes it a dedicated sensor of the very cofactor it consumes.


Evidence Base

PMID Title (abbrev.) Role in this report
24164855 Yeast sirtuins and the regulation of aging Defines sirtuin family enzymatic activity; names Hst1 as a Sir2 homolog (F1)
15274642 Substrate specificity and kinetic mechanism of the Sir2 family Reaction products: nicotinamide + deacetylated product + OAADPr (F1)
16388603 Sir2 protein deacetylases: chemical intermediates & conserved histidine Direct evidence for Ξ±-1β€²-O-alkylamidate intermediate; catalytic His (F1)
12612074 Rfm1, a novel tethering factor… Establishes Sum1–Rfm1–Hst1 architecture; vegetative repression of MSGs (F2)
17242192 Swapping gene-specific and regional silencing specificities of Hst1 and Sir2 Divergence is cofactor specificity, not catalysis (F2)
12972620 Hst1p controls biosynthesis and cellular NAD⁺ levels Hst1 as NAD⁺ sensor repressing de novo BNA genes (F3)
30760525 Mac1, Hst1, and nicotinic acid regulate NAD biosynthesis Additional regulatory link for NAD biosynthesis (F3)
11313477 A novel form of silencing by Sum1-1 requires Hst1 and ORC Hst1 can silence HMR when targeted via Sum1-1/ORC (F4)
27543294 Gene loss & functional divergence of sirtuins in Candida HST1 evolutionarily retained; can regain silencing (F4)
26646153 Genome-wide NAM screen for sirtuin-dependent pathways Genome-stability pathways vulnerable to sirtuin loss (F4)
10562556 Sum1 and Hst1 repress middle sporulation genes during mitosis Gene-specific, non-spreading MSE-based repression (F5)
12832469 Sum1 and Ndt80 compete for MSE binding Meiotic de-repression via Ndt80 competition (F5)
27362276 Ndt80 activates mORC1 and SMA2 via bi-directional MSE Target genes SMA2/mORC1; Sum1 represses in mitosis (F5)
8810037 HST1, a new member of the SIR2 family 71% identity to SIR2; distinct native role (no HMLΞ±/rDNA phenotype) (F6)
14502267 Structure and autoregulation of yeast Hst2 Structural fold applicable to Hst1 by homology; N/C autoregulation (F7)
29543820 Crystal structure of Leishmania Sir2-related protein 1 Confirms Zn subdomain + Rossmann NAD⁺ domain fold (F7)
29066473 Repression of middle sporulation genes Hst1 acts on chromatin locus-specifically; H4K5ac rises on loss (F7, F9)
14729974 Nicotinamide clearance by Pnc1 regulates silencing Pnc1/NAM regulation of Hst1-mediated repression (F8)
11711434 SET3 complex includes Hos2 and Hst1 Hst1 membership in Set3C; also in Sum1 complex (F8)
10693811 Sir2 is an NAD-dependent histone deacetylase Histone lysine substrate specificity (H3K9/K14, H4K16) (F9)
17289592 Structural basis for nicotinamide inhibition and base exchange Hst2 bound to acetyl-H4K16 substrate (F9)
17951578 Acetyl-lysine analog peptides as probes In vitro propionyl-/butyryl-lysine substrates (F9)

How the evidence hangs together: The catalytic identity (F1, F9) is derived from broadly conserved sirtuin biochemistry with structural support from the near-identical paralog Hst2 (F7). The physiological function (F2, F3, F5, F8) rests on Hst1-specific genetic and transcript-profiling studies in S. cerevisiae. The most direct in vivo, Hst1-specific substrate evidence is the locus-specific rise in H4K5ac upon loss of Sum1/Hst1 chromatin association (F7/F9, PMID: 29066473). The negative result that Hst1 disruption causes no HMLΞ±/rDNA phenotype (F6) is essential for correctly bounding the claim: Hst1's native role is gene-specific promoter repression, not regional silencing.


Limitations and Knowledge Gaps

  1. Structural inference by homology. No experimentally solved structure of Hst1 (P53685) itself is cited here; its fold, active site, and autoregulatory extensions are inferred from the paralog Hst2 and other sirtuins (PMID: 14502267, PMID: 17289592). Given 71% identity to Sir2 and close relatedness to Hst2, this inference is strong, but Hst1-specific active-site kinetic constants (Km for NAD⁺, kcat) are only qualitatively described ("relatively low NAD⁺ affinity").

  2. Direct histone-substrate mapping for Hst1 is limited. The most-cited residue-specific in vivo readout is H4K5ac at target loci (PMID: 29066473); the H3K9/K14/H4K16 assignments come from the Sir2 family generally (PMID: 10693811) or from Hst2 structures (PMID: 17289592). A comprehensive, quantitative map of Hst1's preferred histone (and possible non-histone) acetyl-lysine substrates at native promoters is not fully established.

  3. Non-histone substrates. While the family can deacetylate non-histone proteins and longer acyl-lysines in vitro (PMID: 17951578), Hst1's physiological non-histone substrates (if any) are not defined.

  4. Quantitative division of labor between the two Hst1 complexes. Hst1 is in both the Sum1–Rfm1–Hst1 complex and Set3C (PMID: 11711434). The relative contribution of each complex to specific target genes, and the extent of functional overlap with the NAD-independent HDAC Hos2 within Set3C, remain incompletely quantified.

  5. Localization detail. The nuclear/chromatin localization is well supported functionally (recruitment to promoters, locus-specific H4K5ac), but fine-grained genome-wide occupancy (ChIP-seq) data for Hst1 across all conditions is not exhaustively catalogued here.


Proposed Follow-up Experiments / Actions

  1. Determine the Hst1 structure (ideally the Sum1–Rfm1–Hst1 complex on a nucleosome bearing acetyl-H4 tails) by crystallography or cryo-EM to directly visualize substrate engagement and the N-terminal targeting determinants that distinguish Hst1 from Sir2.

  2. Quantitative enzymology of Hst1. Measure Km(NAD⁺), kcat, and nicotinamide Ki for purified Hst1 against defined acetyl-histone peptides/nucleosomes to rigorously establish the "low NAD⁺ affinity" that underlies its sensor function, and compare head-to-head with Sir2, Hst2–4.

  3. Genome-wide, condition-resolved Hst1 substrate mapping. Combine Hst1 ChIP-seq with quantitative histone-PTM proteomics (H4K5ac, H4K16ac, H3K9/K14ac) in wild-type vs. hst1Ξ” across vegetative growth, NAD⁺-limited conditions, and meiotic entry, to build a residue-resolved substrate map at each target promoter.

  4. Test the NAD⁺-sensor feedback loop directly. Titrate cellular NAD⁺ (via BNA/salvage pathway perturbation and PNC1 modulation) and measure Hst1 occupancy, BNA-gene derepression, and NAD⁺ levels to quantify the sensor's set-point and gain.

  5. Dissect the Ndt80–Sum1–Hst1 switch kinetics with time-resolved ChIP through meiosis to determine whether Ndt80 actively evicts the Hst1 repressor or passively wins by mass action at MSEs of key targets (NDT80, IME2, SMA2/mORC1).

  6. Separate Set3C vs. Sum1-complex contributions using complex-specific separation-of-function alleles (e.g., Rfm1-binding vs. Snt1/Set3-binding mutants of Hst1) to assign each target gene to its responsible complex.


Conclusion

HST1 (YOL068C; UniProt P53685) is unambiguously the NAD⁺-dependent protein/histone deacetylase HST1 of Saccharomyces cerevisiae β€” a Class I sirtuin, EC 2.3.1.286, and a Sir2 paralog. All literature reviewed corresponds precisely to this gene and organism; the gene symbol is not ambiguous in this context. Its primary function is gene-specific transcriptional repression of meiotic/middle-sporulation genes as the catalytic subunit of the Sum1–Rfm1–Hst1 complex at MSE promoters, executed by NAD⁺-dependent deacetylation of nucleosomal histone tails in the nucleus, and gated developmentally by Ndt80 competition and metabolically by its role as a low-affinity NAD⁺ sensor that controls de novo NAD⁺ biosynthesis.

Artifacts

Citations

  1. PMID:24164855
  2. PMID:15274642
  3. PMID:16388603
  4. PMID:12612074
  5. PMID:17242192
  6. PMID:12972620
  7. PMID:30760525
  8. PMID:11313477
  9. PMID:27543294
  10. PMID:26646153
  11. PMID:10562556
  12. PMID:12832469
  13. PMID:27362276
  14. PMID:8810037
  15. PMID:14502267
  16. PMID:29543820
  17. PMID:29066473
  18. PMID:14729974
  19. PMID:11711434
  20. PMID:10693811
  21. PMID:17289592
  22. PMID:17951578

πŸ“š Additional Documentation

Notes

(HST1-notes.md)

HST1 review notes

Identity and scope

  • Target: Saccharomyces cerevisiae HST1 / YOL068C, UniProt P53685, a
    503-residue class-I sirtuin. This is the canonical NAD-dependent deacetylase,
    not P50111/YMR273C (Zds1), whose obsolete HST1 synonym caused the former
    repository collision.
  • OpenScientist completed a GO-focused synthesis on 2026-08-12. Its Markdown
    report and HTML/PDF artifacts are preserved in this gene directory.

Core mechanism

  • Hst1 is the catalytic subunit of a locus-specific Sum1-Rfm1-Hst1 repressor.
    Rfm1 bridges Sum1 and Hst1 and is required for their interaction
    [PMID:12612074, "Rfm1 interacts with both Sum1 and Hst1 and is required for
    the Sum1-Hst1 interaction."].
  • The complex represses middle-sporulation genes during vegetative growth.
    Modern chromatin analysis shows that Sum1 and Hst1 remain associated with
    these loci and maintain deacetylation primarily at H4K5
    [PMID:29066473, "Set1 appeared to promote the association of the
    sequence-specific DNA binding protein Sum1 and the HDAC Hst1 with middle
    sporulation genes to maintain deacetylation, primarily at H4K5, and gene
    repression."].
  • Hst1 also couples intracellular NAD+ to repression of de novo NAD
    biosynthesis and thiamine-biosynthesis genes. These are genuine target
    programs of the same promoter-deacetylation mechanism rather than distinct
    catalytic functions [PMID:20439498, "multiple thiamine ( THI ) genes in
    Saccharomyces cerevisiae are also regulated by the intracellular NAD +
    concentration via the NAD + -dependent histone deacetylase (HDAC) Hst1"].
  • Sum1 recruits Hst1 to a subset of replication origins, where loss of Hst1
    increases H4K5 acetylation and reduces initiation efficiency
    [PMID:18990212, "We identified seven ARS elements whose initiation capacity
    depended on Sum1 and Hst1."]. This direct extra role is retained as non-core.

Native versus conditional silencing

  • Native Hst1 is not a Sir2-like regional silencing enzyme. The original HST1
    characterization reports no phenotype in Sir2-dependent HML or rDNA
    silencing [PMID:8810037, "Disruption of HST1 has shown no phenotype with
    respect to mechanisms in which SIR2 has a role, namely, regional silencing
    of HML alpha, or in rDNA recombination."]. The telomeric-region and
    subtelomeric-heterochromatin inferences are therefore removed.
  • Hst1 can silence HMR when the gain-of-function Sum1-1 protein aberrantly
    recruits it. Those experimental mating-type-silencing annotations are kept
    as conditional/non-core rather than treated as Hst1's native function.
  • PMID:27185881 and PMID:16051752 are abstract-only caches whose visible text
    does not expose the Hst1 experiments underlying two curated annotations.
    Those experimental calls remain UNDECIDED; the review does not overrule
    curators from incomplete evidence.

Annotation synthesis

  • Core molecular function: NAD-dependent histone deacetylase activity
    (GO:0017136), acting in the Sum1-Rfm1-Hst1 histone deacetylase complex.
  • Core process and location: negative regulation of DNA-templated
    transcription on nuclear chromatin.
  • H3K9-, H3K14-, and H4K16-specific IBA activities are marked
    over-annotated. Hst1-specific studies identify H4K5 as the predominant
    residue. Current GO has an H4K5 hydrolytic-mechanism term but no
    NAD-dependent H4K5 child of GO:0017136, so the review proposes that missing
    term while retaining the generic NAD-dependent activity as the core function.
  • PMID:12972620 directly demonstrates Hst1-dependent repression of de novo NAD+
    biosynthesis genes. Existing GO:1905013, negative regulation of 'de novo' NAD
    biosynthetic process from L-tryptophan, represents the yeast BNA route; use it
    rather than proposing a duplicate process term.
  • Set3C membership is experimentally real, but Hst1 is largely dispensable for
    Set3C repression and the Sum1-Rfm1-Hst1 complex is its principal functional
    context. Set3C annotations are retained as non-core.
  • Generic protein binding annotations are marked over-annotated; specific
    recruitment by Rfm1 and complex membership are biologically informative.

πŸ“„ View Raw YAML

id: P53685
gene_symbol: HST1
product_type: PROTEIN
status: DRAFT
taxon:
  id: NCBITaxon:559292
  label: Saccharomyces cerevisiae
description: >-
  HST1 encodes a nuclear NAD-dependent sirtuin deacetylase that is recruited by
  Sum1 and the tethering factor Rfm1 to selected chromosomal loci. Local histone
  deacetylation, prominently at H4K5, represses middle-sporulation and metabolic
  gene programs during vegetative growth and also supports efficient initiation
  at a subset of replication origins. Unlike its paralog Sir2, native Hst1 is a
  gene-specific chromatin regulator rather than a regional silencing factor at
  telomeres or silent mating-type loci.
existing_annotations:
- term:
    id: GO:0005634
    label: nucleus
  evidence_type: IBA
  original_reference_id: GO_REF:0000033
  qualifier: is_active_in
  review:
    summary: Hst1 is a nuclear chromatin-associated sirtuin recruited to specific promoters
      and replication origins.
    action: ACCEPT
    reason: Nuclear localization and locus-specific chromatin association are supported
      by PMID:11711434 and PMID:29066473.
- term:
    id: GO:0006974
    label: DNA damage response
  evidence_type: IBA
  original_reference_id: GO_REF:0000033
  qualifier: involved_in
  review:
    summary: A DNA-damage-response role has not been demonstrated for Hst1 itself.
    action: MARK_AS_OVER_ANNOTATED
    reason: This IBA appears to transfer a broad Sir2-family genome-stability role without
      positive Hst1-specific evidence; Hst1's demonstrated functions are locus-specific
      deacetylation and transcriptional repression.
- term:
    id: GO:0003714
    label: transcription corepressor activity
  evidence_type: IBA
  original_reference_id: GO_REF:0000033
  qualifier: enables
  review:
    summary: Hst1 provides catalytic repression within the Sum1-Rfm1-Hst1 complex.
    action: ACCEPT
    reason: Rfm1 recruits Hst1 to Sum1-bound promoters to repress middle-sporulation genes
      (PMID:12612074).
    supported_by:
    - reference_id: PMID:12612074
      supporting_text: Rfm1 interacts with both Sum1 and Hst1 and is required for the
        Sum1-Hst1 interaction.
      reference_section_type: ABSTRACT
- term:
    id: GO:0031509
    label: subtelomeric heterochromatin formation
  evidence_type: IBA
  original_reference_id: GO_REF:0000033
  qualifier: involved_in
  review:
    summary: Native Hst1 is a gene-specific repressor, not a telomeric regional-silencing
      enzyme.
    action: REMOVE
    reason: Hst1 and Sir2 have distinct cofactor-targeting specificities; PMID:17242192
      assigns telomeric regional silencing to Sir2-Sir3-Sir4 and gene-specific repression
      to Hst1-Rfm1-Sum1. This IBA transfers the Sir2 role to Hst1.
    supported_by:
    - reference_id: PMID:17242192
      supporting_text: Nevertheless, the two proteins promote two mechanistically distinct
        forms of gene repression.
      reference_section_type: ABSTRACT
- term:
    id: GO:0032041
    label: histone H3K14 deacetylase activity, NAD-dependent
  evidence_type: IBA
  original_reference_id: GO_REF:0000033
  qualifier: enables
  review:
    summary: Hst1 deacetylates promoter histones, but H3K14 specificity has not been demonstrated
      for Hst1 itself.
    action: MARK_AS_OVER_ANNOTATED
    reason: Hst1-specific chromatin studies identify H4K5 as the predominant affected
      residue; this residue-specific IBA overextends broader sirtuin evidence. The proposed
      NAD-dependent H4K5 term records the supported specificity.
    supported_by:
    - reference_id: PMID:18990212
      supporting_text: This was consistent with the notion that H4 K5 was the main target
        of the histone deacetylase Hst1, whereas other histone H4 lysine residues were
        minor or no targets of Hst1.
      reference_section_type: RESULTS
- term:
    id: GO:0046969
    label: histone H3K9 deacetylase activity, NAD-dependent
  evidence_type: IBA
  original_reference_id: GO_REF:0000033
  qualifier: enables
  review:
    summary: Hst1 is an NAD-dependent histone deacetylase, but H3K9 specificity is not
      established for Hst1.
    action: MARK_AS_OVER_ANNOTATED
    reason: The H3K9 assignment derives from family transfer, whereas Hst1-specific experiments
      primarily implicate H4K5. The proposed NAD-dependent H4K5 term records the supported
      specificity.
    supported_by:
    - reference_id: PMID:18990212
      supporting_text: This was consistent with the notion that H4 K5 was the main target
        of the histone deacetylase Hst1, whereas other histone H4 lysine residues were
        minor or no targets of Hst1.
      reference_section_type: RESULTS
- term:
    id: GO:0046970
    label: histone H4K16 deacetylase activity, NAD-dependent
  evidence_type: IBA
  original_reference_id: GO_REF:0000033
  qualifier: enables
  review:
    summary: H4K16 can be affected at selected Hst1-regulated origins, but it is not a
      general Hst1 substrate.
    action: MARK_AS_OVER_ANNOTATED
    reason: PMID:18990212 explicitly found H4K16 was not a general Hst1 target; H4K5 was
      the main residue affected. The proposed NAD-dependent H4K5 term records the supported
      specificity.
    supported_by:
    - reference_id: PMID:18990212
      supporting_text: Similarly, our analysis indicated that H4 K16 was not a general
        target of deacetylation by Hst1.
      reference_section_type: RESULTS
- term:
    id: GO:0000781
    label: chromosome, telomeric region
  evidence_type: IEA
  original_reference_id: GO_REF:0000108
  qualifier: located_in
  review:
    summary: Hst1 acts at selected nuclear loci but is not normally a telomere-associated
      silencing factor.
    action: REMOVE
    reason: This GO_REF:0000108 IEA is derived mechanically from GO:0031509. PMID:17242192
      instead assigns telomeric regional silencing to Sir2-Sir3-Sir4 and gene-specific
      repression to Hst1-Rfm1-Sum1.
    supported_by:
    - reference_id: PMID:17242192
      supporting_text: Hst1 interacts with Rfm1 and Sum1 to repress the transcription
        of specific middle-sporulation genes.
      reference_section_type: ABSTRACT
- term:
    id: GO:0000785
    label: chromatin
  evidence_type: IEA
  original_reference_id: GO_REF:0000117
  qualifier: located_in
  review:
    summary: Hst1 is recruited to chromatin at Sum1-regulated promoters and selected replication
      origins.
    action: ACCEPT
    reason: Chromatin association and locus-specific loss of Hst1 binding are directly
      demonstrated in PMID:29066473.
- term:
    id: GO:0005634
    label: nucleus
  evidence_type: IEA
  original_reference_id: GO_REF:0000044
  qualifier: located_in
  review:
    summary: Hst1 localizes to the nucleus, where it acts on promoter chromatin.
    action: ACCEPT
    reason: Nuclear localization is experimentally supported and coherent with its chromatin-targeted
      repression.
- term:
    id: GO:0017136
    label: histone deacetylase activity, NAD-dependent
  evidence_type: IEA
  original_reference_id: GO_REF:0000117
  qualifier: enables
  review:
    summary: NAD-dependent histone deacetylation is Hst1's core catalytic activity.
    action: ACCEPT
    reason: Direct genetic and biochemical studies establish Hst1-dependent histone deacetylation
      (PMID:11313477; PMID:12972620).
    supported_by:
    - reference_id: PMID:12972620
      supporting_text: The NAD(+)-dependent deacetylase activity of Hst1p represses de
        novo NAD(+) biosynthesis genes in the absence of new protein synthesis, suggesting
        a direct effect.
      reference_section_type: ABSTRACT
- term:
    id: GO:0030466
    label: silent mating-type cassette heterochromatin formation
  evidence_type: IEA
  original_reference_id: GO_REF:0000117
  qualifier: involved_in
  review:
    summary: Hst1 can support HMR silencing in engineered Sum1-1 or sensitized backgrounds,
      but this is not its normal physiological role.
    action: MARK_AS_OVER_ANNOTATED
    reason: The unqualified IEA obscures that Hst1-dependent mating-type silencing is
      conditional on altered targeting rather than native regional silencing.
    supported_by:
    - reference_id: PMID:11313477
      supporting_text: Sum1-1 requires the Sir2 homolog, Hst1, for silencing and most
        probably requires the NAD(+)-dependent deacetylase activity of this protein.
      reference_section_type: ABSTRACT
- term:
    id: GO:0031981
    label: nuclear lumen
  evidence_type: IEA
  original_reference_id: GO_REF:0000117
  qualifier: located_in
  review:
    summary: Nuclear lumen is a correct broad localization but less informative than nucleus/chromatin.
    action: KEEP_AS_NON_CORE
    reason: The location is compatible with experimental nuclear localization but does
      not describe the locus-targeted activity.
- term:
    id: GO:0034979
    label: NAD-dependent protein lysine deacetylase activity
  evidence_type: IEA
  original_reference_id: GO_REF:0000120
  qualifier: enables
  review:
    summary: Hst1 catalyzes NAD-dependent lysine deacetylation of protein substrates,
      physiologically including promoter histones.
    action: ACCEPT
    reason: This activity-level term accurately captures the sirtuin reaction without
      overcommitting to an unsupported histone residue.
    supported_by:
    - reference_id: PMID:12972620
      supporting_text: The NAD(+)-dependent deacetylase activity of Hst1p represses de
        novo NAD(+) biosynthesis genes in the absence of new protein synthesis, suggesting
        a direct effect.
      reference_section_type: ABSTRACT
- term:
    id: GO:0045892
    label: negative regulation of DNA-templated transcription
  evidence_type: IEA
  original_reference_id: GO_REF:0000108
  qualifier: involved_in
  review:
    summary: Hst1 represses specific RNA polymerase II transcription programs through
      promoter histone deacetylation.
    action: ACCEPT
    reason: Middle-sporulation, NAD-biosynthesis, and thiamine-biosynthesis genes are
      directly repressed by Hst1. The NAD-biosynthesis program is represented more specifically
      by existing GO:1905013, negative regulation of 'de novo' NAD biosynthetic process
      from L-tryptophan.
    supported_by:
    - reference_id: PMID:10562556
      supporting_text: SUM1 and HST1, genes previously associated with transcriptional
        silencing, are required for MSE-mediated repression.
      reference_section_type: ABSTRACT
- term:
    id: GO:0045910
    label: negative regulation of DNA recombination
  evidence_type: IEA
  original_reference_id: GO_REF:0000117
  qualifier: involved_in
  review:
    summary: A broad negative-regulation-of-recombination role is not supported for Hst1.
    action: MARK_AS_OVER_ANNOTATED
    reason: The directly tested hst1 disruption had no rDNA recombination phenotype.
      The separate mitotic-recombination IMP remains UNDECIDED pending its inaccessible
      full-text evidence, but it does not justify this broad electronic assignment.
    supported_by:
    - reference_id: PMID:8810037
      supporting_text: Disruption of HST1 has shown no phenotype with respect to mechanisms
        in which SIR2 has a role, namely, regional silencing of HML alpha, or in rDNA
        recombination.
      reference_section_type: ABSTRACT
- term:
    id: GO:0070403
    label: NAD+ binding
  evidence_type: IEA
  original_reference_id: GO_REF:0000002
  qualifier: enables
  review:
    summary: NAD+ binding is intrinsic to the Hst1 sirtuin catalytic cycle.
    action: ACCEPT
    reason: Hst1 consumes NAD+ during deacetylation, and PMID:12972620 directly reports
      its comparatively low NAD+ affinity.
    supported_by:
    - reference_id: PMID:12972620
      supporting_text: In vitro experiments demonstrate that Hst1p has relatively low
        affinity toward NAD(+) in comparison to other NAD(+)-dependent enzymes.
      reference_section_type: ABSTRACT
- term:
    id: GO:0005515
    label: protein binding
  evidence_type: IPI
  original_reference_id: PMID:12612074
  qualifier: enables
  review:
    summary: The Rfm1-Hst1 interaction recruits Hst1 to Sum1-bound promoters, but generic
      protein binding is uninformative.
    action: MARK_AS_OVER_ANNOTATED
    reason: PMID:12612074 supports a specific tethering interaction that GO:0005515 fails
      to represent.
- term:
    id: GO:0005515
    label: protein binding
  evidence_type: IPI
  original_reference_id: PMID:16429126
  qualifier: enables
  review:
    summary: A high-throughput interaction does not define Hst1's molecular function.
    action: MARK_AS_OVER_ANNOTATED
    reason: Generic protein binding should not replace the specific NAD-dependent deacetylase
      and corepressor activities.
- term:
    id: GO:0005515
    label: protein binding
  evidence_type: IPI
  original_reference_id: PMID:37968396
  qualifier: enables
  review:
    summary: Proteome-scale interaction evidence does not justify generic protein binding
      as an informative function.
    action: MARK_AS_OVER_ANNOTATED
    reason: Hst1's mechanistic partners and catalytic activity are already represented
      more specifically.
- term:
    id: GO:0005634
    label: nucleus
  evidence_type: IDA
  original_reference_id: PMID:11711434
  qualifier: located_in
  review:
    summary: Hst1 is experimentally localized to the nucleus.
    action: ACCEPT
    reason: The Set3C study and independent localization data support nuclear localization.
- term:
    id: GO:0006974
    label: DNA damage response
  evidence_type: NAS
  original_reference_id: PMID:11711434
  qualifier: involved_in
  review:
    summary: PMID:11711434 establishes Hst1-containing deacetylase complexes but not a
      direct Hst1 DNA-damage-response role.
    action: MARK_AS_OVER_ANNOTATED
    reason: This ComplexPortal-associated NAS extends chromatin-complex membership to a
      process not demonstrated for Hst1 in the cited paper.
- term:
    id: GO:0009267
    label: cellular response to starvation
  evidence_type: NAS
  original_reference_id: PMID:11711434
  qualifier: involved_in
  review:
    summary: Nutrient state modulates Hst1-regulated sporulation and metabolic transcription
      programs.
    action: KEEP_AS_NON_CORE
    reason: Starvation response is biologically relevant to relief of sporulation repression
      but is downstream of Hst1's catalytic core function.
- term:
    id: GO:0034967
    label: Set3 complex
  evidence_type: IPI
  original_reference_id: PMID:11711434
  qualifier: part_of
  review:
    summary: Hst1 is an experimentally identified Set3C subunit, although it is largely
      dispensable for Set3C repression.
    action: KEEP_AS_NON_CORE
    reason: PMID:11711434 places Hst1 in Set3C but identifies the Sum1-Rfm1-Hst1 complex
      as the stronger Hst1-dependent context.
    supported_by:
    - reference_id: PMID:11711434
      supporting_text: The S. cerevisiae SET3 complex includes two histone deacetylases,
        Hos2 and Hst1, and is a meiotic-specific repressor of the sporulation gene program.
      reference_section_type: TITLE
- term:
    id: GO:0045835
    label: negative regulation of meiotic nuclear division
  evidence_type: IDA
  original_reference_id: PMID:11711434
  qualifier: involved_in
  review:
    summary: Hst1 represses middle-sporulation genes during vegetative growth, but direct
      negative regulation of meiotic nuclear division overstates that transcriptional role.
    action: MARK_AS_OVER_ANNOTATED
    reason: The cited Set3C study reports that Hst1 is not required for meiotic repression
      by Set3C; the supported Hst1 role is gene-specific repression through Sum1-Rfm1.
    supported_by:
    - reference_id: PMID:11711434
      supporting_text: However, Hst1 is not required for meiotic repression by Set3C,
        thus implying that Set3C (-Hst1) and not Hst1-Sum1, is the meiotic-specific repressor.
      reference_section_type: ABSTRACT
- term:
    id: GO:0000118
    label: histone deacetylase complex
  evidence_type: IPI
  original_reference_id: PMID:11711434
  qualifier: part_of
  review:
    summary: Hst1 is the catalytic subunit of promoter-targeted histone deacetylase complexes.
    action: ACCEPT
    reason: Physical association with Sum1-Rfm1 and Set3C supports membership in histone
      deacetylase complexes.
- term:
    id: GO:0006357
    label: regulation of transcription by RNA polymerase II
  evidence_type: NAS
  original_reference_id: PMID:12612074
  qualifier: involved_in
  review:
    summary: Hst1 regulates selected RNA polymerase II genes through local chromatin deacetylation.
    action: ACCEPT
    reason: PMID:12612074 directly links Sum1-Rfm1 recruitment of Hst1 to repression of
      middle-sporulation genes.
    supported_by:
    - reference_id: PMID:10562556
      supporting_text: SUM1 and HST1, genes previously associated with transcriptional
        silencing, are required for MSE-mediated repression.
      reference_section_type: ABSTRACT
- term:
    id: GO:0030174
    label: regulation of DNA-templated DNA replication initiation
  evidence_type: NAS
  original_reference_id: PMID:18990212
  qualifier: involved_in
  review:
    summary: Hst1 promotes efficient initiation at a subset of Sum1-bound replication
      origins through histone deacetylation.
    action: KEEP_AS_NON_CORE
    reason: PMID:18990212 provides direct Hst1-specific evidence, but origin control is
      secondary to promoter repression.
    supported_by:
    - reference_id: PMID:18990212
      supporting_text: We identified seven ARS elements whose initiation capacity depended
        on Sum1 and Hst1.
      reference_section_type: ABSTRACT
- term:
    id: GO:0043937
    label: regulation of sporulation
  evidence_type: NAS
  original_reference_id: PMID:12612074
  qualifier: involved_in
  review:
    summary: Hst1 represses middle-sporulation genes during vegetative growth and thereby
      regulates the sporulation program.
    action: ACCEPT
    reason: Sum1-Rfm1 recruits Hst1 to these promoters, and loss of the complex derepresses
      the program (PMID:12612074).
    supported_by:
    - reference_id: PMID:10562556
      supporting_text: SUM1 and HST1, genes previously associated with transcriptional
        silencing, are required for MSE-mediated repression.
      reference_section_type: ABSTRACT
- term:
    id: GO:0008270
    label: zinc ion binding
  evidence_type: RCA
  original_reference_id: PMID:30358795
  qualifier: enables
  review:
    summary: Hst1 contains the conserved structural zinc-binding subdomain of sirtuins.
    action: ACCEPT
    reason: Zinc binding is a conserved structural feature of the sirtuin catalytic domain
      and is consistent with the Hst1 sequence/domain annotation.
- term:
    id: GO:0017136
    label: histone deacetylase activity, NAD-dependent
  evidence_type: IDA
  original_reference_id: PMID:11313477
  qualifier: enables
  review:
    summary: Hst1-dependent NAD-dependent histone deacetylase activity is required for
      engineered Sum1-1 silencing.
    action: ACCEPT
    reason: PMID:11313477 directly tested the requirement for Hst1 in this conditional
      silencing system.
- term:
    id: GO:0017136
    label: histone deacetylase activity, NAD-dependent
  evidence_type: IDA
  original_reference_id: PMID:11711434
  qualifier: enables
  review:
    summary: Hst1 is one of the histone deacetylases identified in Set3C.
    action: ACCEPT
    reason: PMID:11711434 experimentally identifies Hst1 in the complex and supports NAD-dependent
      histone deacetylase activity.
- term:
    id: GO:0030466
    label: silent mating-type cassette heterochromatin formation
  evidence_type: IGI
  original_reference_id: PMID:27185881
  qualifier: involved_in
  review:
    summary: The study concerns Sir2-mediated silent-chromatin cohesion; the cached abstract
      is insufficient to verify the Hst1 genetic interaction.
    action: UNDECIDED
    reason: Preserve the curator's experimental IGI annotation pending access to the full
      supporting evidence; do not infer misattribution from an abstract centered on Sir2.
- term:
    id: GO:0030466
    label: silent mating-type cassette heterochromatin formation
  evidence_type: IMP
  original_reference_id: PMID:11313477
  qualifier: involved_in
  review:
    summary: Hst1 is required for HMR silencing when recruited by the gain-of-function
      Sum1-1 protein.
    action: KEEP_AS_NON_CORE
    reason: PMID:11313477 supports the annotation in this engineered context, but native
      Hst1 does not normally perform regional mating-type silencing.
- term:
    id: GO:0030466
    label: silent mating-type cassette heterochromatin formation
  evidence_type: IGI
  original_reference_id: PMID:11313477
  qualifier: involved_in
  review:
    summary: Genetic evidence supports Hst1-dependent Sum1-1 silencing at HMR.
    action: KEEP_AS_NON_CORE
    reason: Retain the experimentally curated interaction while making the non-native
      targeting context explicit.
- term:
    id: GO:0034967
    label: Set3 complex
  evidence_type: IDA
  original_reference_id: PMID:11711434
  qualifier: part_of
  review:
    summary: Hst1 is an experimentally identified Set3C component.
    action: KEEP_AS_NON_CORE
    reason: Set3C membership is real, but Hst1 is not essential for the complex's meiotic
      repression and its main complex is Sum1-Rfm1-Hst1.
- term:
    id: GO:0045950
    label: negative regulation of mitotic recombination
  evidence_type: IMP
  original_reference_id: PMID:16051752
  qualifier: involved_in
  review:
    summary: The cached abstract focuses on Hst2-mediated lifespan regulation and does
      not expose the experiment supporting Hst1-dependent recombination control.
    action: UNDECIDED
    reason: The IMP annotation should not be overruled without the relevant full-text
      evidence; retain for curator follow-up.
- term:
    id: GO:0070623
    label: regulation of thiamine biosynthetic process
  evidence_type: IMP
  original_reference_id: PMID:20439498
  qualifier: involved_in
  review:
    summary: Hst1 links NAD+ availability to basal repression of thiamine biosynthesis
      genes.
    action: KEEP_AS_NON_CORE
    reason: PMID:20439498 directly supports this extra program, but it is one target set
      of the broader Hst1 promoter-repression mechanism.
    supported_by:
    - reference_id: PMID:20439498
      supporting_text: We have determined that multiple thiamine ( THI ) genes in Saccharomyces
        cerevisiae are also regulated by the intracellular NAD + concentration via the
        NAD + -dependent histone deacetylase (HDAC) Hst1 and, to a lesser extent, Sir2.
      reference_section_type: ABSTRACT
core_functions:
- description: >-
    Hst1 is the NAD-dependent histone deacetylase of the Sum1-Rfm1-Hst1
    transcriptional repressor. Sum1 specifies target loci and Rfm1 recruits Hst1,
    whose local deacetylation of promoter chromatin, predominantly H4K5, represses
    middle-sporulation and selected metabolic genes during vegetative growth.
  molecular_function:
    id: GO:0017136
    label: histone deacetylase activity, NAD-dependent
  directly_involved_in:
  - id: GO:0045892
    label: negative regulation of DNA-templated transcription
  locations:
  - id: GO:0000785
    label: chromatin
  - id: GO:0005634
    label: nucleus
  in_complex:
    id: GO:0000118
    label: histone deacetylase complex
  supported_by:
  - reference_id: PMID:12612074
    supporting_text: Rfm1 interacts with both Sum1 and Hst1 and is required for the Sum1-Hst1 interaction.
    reference_section_type: ABSTRACT
  - reference_id: PMID:29066473
    supporting_text: Set1 appeared to promote the association of the sequence-specific DNA binding protein Sum1 and the HDAC Hst1 with middle sporulation genes to maintain deacetylation, primarily at H4K5, and gene repression.
    reference_section_type: ABSTRACT
proposed_new_terms:
- proposed_name: histone H4K5 deacetylase activity, NAD-dependent
  proposed_definition: >-
    Catalysis of the removal of an acetyl group from lysine 5 of histone H4 using
    NAD+ as a reactant, producing deacetylated histone, nicotinamide, and
    2'-O-acetyl-ADP-ribose.
  justification: >-
    Current GO has an H4K5-specific term for the hydrolytic mechanism and several
    residue-specific NAD-dependent histone deacetylase terms, but no NAD-dependent
    H4K5 child of GO:0017136. Hst1-specific experiments identify H4K5 as its main
    histone H4 target.
  proposed_parent:
    id: GO:0017136
    label: histone deacetylase activity, NAD-dependent
  supported_by:
  - reference_id: PMID:18990212
    supporting_text: This was consistent with the notion that H4 K5 was the main target
      of the histone deacetylase Hst1, whereas other histone H4 lysine residues were
      minor or no targets of Hst1.
    reference_section_type: RESULTS
suggested_questions:
- question: >-
    Which endogenous Hst1 target proteins, if any, are deacetylated outside
    chromatin, and do such substrates account for the secondary DNA-damage and
    recombination phenotypes assigned to the Sir2 family?
- question: >-
    How does the Sum1-Rfm1-Hst1 complex choose between middle-sporulation,
    NAD-biosynthesis, thiamine-biosynthesis, and replication-origin targets as
    nutrient state and intracellular NAD+ change?
suggested_experiments:
- hypothesis: >-
    H4K5 is the dominant physiological histone substrate of promoter-bound Hst1,
    whereas the H3K9, H3K14, and H4K16 residue-specific IBA assignments are not
    broadly applicable to native Hst1 targets.
  description: >-
    Combine acute Hst1 depletion with calibrated residue-specific histone
    acetylation profiling and Hst1/Sum1 ChIP-seq across vegetative, NAD-limited,
    and sporulation-inducing conditions, then test catalytic-dead Hst1 rescue at
    directly bound loci.
  experiment_type: acute depletion, quantitative histone acetyl-proteomics, and ChIP-seq
references:
- id: GO_REF:0000002
  title: Gene Ontology annotation through association of InterPro records with GO
    terms
  findings: []
- id: GO_REF:0000033
  title: Annotation inferences using phylogenetic trees
  findings: []
- id: GO_REF:0000044
  title: Gene Ontology annotation based on UniProtKB/Swiss-Prot Subcellular Location
    vocabulary mapping, accompanied by conservative changes to GO terms applied by
    UniProt
  findings: []
- id: GO_REF:0000108
  title: Automatic assignment of GO terms using logical inference, based on on inter-ontology
    links
  findings: []
- id: GO_REF:0000117
  title: Electronic Gene Ontology annotations created by ARBA machine learning models
  findings: []
- id: GO_REF:0000120
  title: Combined Automated Annotation using Multiple IEA Methods
  findings: []
- id: file:yeast/HST1/HST1-deep-research-openscientist.md
  title: OpenScientist GO-focused literature synthesis for yeast HST1
  findings: []
- id: PMID:8810037
  title: HST1, a new member of the SIR2 family of genes.
  findings: []
  reference_review:
    relevance: HIGH
    correctness: VERIFIED
    review_notes: >-
      PubMed-verified primary study; the abstract directly reports the negative
      HST1 results for HML regional silencing and rDNA recombination used in this review.
- id: PMID:10562556
  title: Sum1 and Hst1 repress middle sporulation-specific gene expression during mitosis in Saccharomyces cerevisiae.
  findings: []
- id: PMID:12972620
  title: NAD+-dependent deacetylase Hst1p controls biosynthesis and cellular NAD+ levels in Saccharomyces cerevisiae.
  findings: []
- id: PMID:17242192
  title: Swapping the gene-specific and regional silencing specificities of the Hst1 and Sir2 histone deacetylases.
  findings: []
  reference_review:
    relevance: HIGH
    correctness: VERIFIED
    review_notes: >-
      PubMed-verified primary study; directly distinguishes Hst1-Rfm1-Sum1
      gene-specific repression from Sir2-Sir3-Sir4 regional silencing.
- id: PMID:29066473
  title: Repression of Middle Sporulation Genes in Saccharomyces cerevisiae by the Sum1-Rfm1-Hst1 Complex Is Maintained by Set1 and H3K4 Methylation.
  findings: []
- id: PMID:11313477
  title: A novel form of transcriptional silencing by Sum1-1 requires Hst1 and the
    origin recognition complex.
  findings: []
- id: PMID:11711434
  title: The S. cerevisiae SET3 complex includes two histone deacetylases, Hos2 and
    Hst1, and is a meiotic-specific repressor of the sporulation gene program.
  findings: []
- id: PMID:12612074
  title: Rfm1, a novel tethering factor required to recruit the Hst1 histone deacetylase
    for repression of middle sporulation genes.
  findings: []
- id: PMID:16051752
  title: HST2 mediates SIR2-independent life-span extension by calorie restriction.
  findings: []
- id: PMID:16429126
  title: Proteome survey reveals modularity of the yeast cell machinery.
  findings: []
- id: PMID:18990212
  title: Control of replication initiation by the Sum1/Rfm1/Hst1 histone deacetylase.
  findings: []
  reference_review:
    relevance: HIGH
    correctness: VERIFIED
    review_notes: >-
      Full text verified; directly supports Hst1-dependent replication-origin
      control and the H4K5-predominant substrate-specificity conclusions.
- id: PMID:20439498
  title: Thiamine biosynthesis in Saccharomyces cerevisiae is regulated by the NAD+-dependent
    histone deacetylase Hst1.
  findings: []
- id: PMID:27185881
  title: Determinants of Sir2-Mediated, Silent Chromatin Cohesion.
  findings: []
- id: PMID:30358795
  title: The cellular economy of the Saccharomyces cerevisiae zinc proteome.
  findings: []
- id: PMID:37968396
  title: The social and structural architecture of the yeast protein interactome.
  findings: []